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Cost Effective Chemical Oxidative Synthesis of Soluble and Electroactive Polyaniline Salt and Its Application as Anticorrosive Agent for Steel

Affiliation/Institute
Institute of Chemical Sciences, University of Peshawar, Peshawar 25120, Pakistan. anwarulhaqalishah@uop.edu.pk.
Shah, Anwar-Ul-Haq Ali;
Affiliation/Institute
Institute of Chemical Sciences, University of Peshawar, Peshawar 25120, Pakistan. kamranics@uop.edu.pk.
Kamran, Muhammad;
GND
133643379
Affiliation/Institute
TU Braunschweig Institute of Energy and Process Systems Engineering
Bilal, Salma;
Affiliation/Institute
NationalCentre of Excellence in Physical Chemistry, University of Peshawar, Peshawar 25120, Pakistan. srizvi2007@hotmail.com.
Ullah, Rizwan

The cost effective synthesis of electroactive polyaniline (PANI) while retaining its desirable properties is one of the most debatable and challenging tasks for researchers in the field. Herein, we report a cost effective inverse emulsion polymerization pathway for the synthesis of soluble and processable PANI salt by using diesel as a novel dispersion medium. Different reaction parameters and their effects on the properties and yield of polyaniline were optimized. The polymer exhibited a highly porous morphology and was found to be stable up to 417 °C. The PANI salt showed good solubility in common solvents, such as chloroform, N-Methyl-2-pyrrolidone (NMP), dimethyl sulphoxide (DMSO) and in a 1:3 mixtures by volume of 2-propanol and toluene. The coating of the synthesized PANI salt on stainless steel has shown good corrosion resistant behavior in marine water by reducing the corrosion rate to 67.9% as compared to uncoated stainless steel.

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