Crystal structure of 4,6-di­methyl-2-{[3,4,5-trihy­dr­oxy-6-(hy­dr­oxy­meth­yl)tetra­hydro-2H-pyran-2-yl]sulfan­yl}nicotino­nitrile

Masoud, Doaa M.; Hammad, Sherif F.; Elgemeie, Galal H.; Jones, Peter G. GND

In the title compound, C14H18N2O5S, the C—S bond lengths are unequal, with S—Cglucose = 1.8016 (15) Å and S—Cpyrid­yl = 1.7723 (13) Å. The hydro­philic glucose residues lie in the regions z ≃ 0.25 and 0.75. Four classical hydrogen bonds link the mol­ecules to form layers parallel to the ab plane, from which the pyridyl rings project; pyridyl ring stacking parallel to the a axis links adjacent layers.

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Masoud, Doaa M. / Hammad, Sherif / Elgemeie, Galal H. / et al: Crystal structure of 4,6-di­methyl-2-{[3,4,5-trihy­dr­oxy-6-(hy­dr­oxy­meth­yl)tetra­hydro-2H-pyran-2-yl]sulfan­yl}nicotino­nitrile. Braunschweig 2017.

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