Crystal structure of the 1:2 adduct of bis­­(piperidinium) sulfate and 1,3-di­methyl­thio­urea

Döring, Cindy GND; Lueck, Julian F. D. GND; Jones, Peter G. GND

In the title compound, 2C5H12N+·SO42−·2C3H8N2S, the C=S groups of the two independent 1,3-di­methyl­urea mol­ecules and the sulfur atom of the anion lie on twofold axes. The packing is centred on bis­(piperidinium) sulfate ribbons parallel to the c axis; the cations are hydrogen bonded to the sulfate by N—H⋯O and C—H⋯O inter­actions. The 1,3-di­methyl­urea mol­ecules are also hydrogen bonded to sulfate O atoms, and project outwards from the ribbon parallel to the b axis.

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Döring, Cindy / Lueck, Julian F. D. / Jones, Peter: Crystal structure of the 1:2 adduct of bis­­(piperidinium) sulfate and 1,3-di­methyl­thio­urea. Braunschweig 2017.

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